Electrogenerated chemiluminescence of poly[(2,2′-bipyridyl)(4-(2-pyrrol-1-ylethyl)-4′-methyl-2,2′-bipyridyl)2]ruthenium (II) film
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منابع مشابه
2-Methoxyphenyl 2-{2-[1-methyl-5-(4-methylbenzoyl)pyrrol-2-yl]acetamido}acetate
The title compound, amtolmetin guacil, C(24)H(24)N(2)O(5), is a new gastroprotective non-steroidal anti-inflammatory drug. In the crystal structure, the drug mol-ecule is linked into a one-dimensional structure along the c axis by weak N-H⋯O inter-actions between the amide groups. C-H⋯O and C-H⋯π inter-actions influence the packing.
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The electrogenerated chemiluminescence (ecl) produced in acetonitrile-water solutions (1: 1 by volume) by the reaction of electrogenerated Ru(bpy),+ with the strongly oxidizing intermediate, SO4--, generated during reduction of S208” is described. The orange luminescence (A, = 625 nm) corresponds to emission from R~(bpy) ,~+*. The relative ecl intensity is a function of S20s2concentration, and ...
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There are two independent mol-ecules in the asymmetric unit of the title compound, C13H14N2, in which the dihedral angles formed by the pyrrole and benzene rings are 83.63 (8) and 87.84 (8)°. In the crystal, mol-ecules are linked via pairs of N-H⋯N hydrogen bonds, forming inversion dimers, which are further connected by C-H⋯π inter-actions.
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In the N-substituted benzoyl-thio-urea, C(24)H(23)N(5)OS, the benzoyl-thio-urea unit is non-planar (r.m.s. deviation = 0.126 Å). The aliphatic part of the tetra-hydro-quinoline fused-ring system is disordered over two positions in a 0.592 (5):0.408 (5) ratio. The pyridine and pyrrole rings are twisted by 55.2 (1)° in order to avoid crowding of their respective substituents. Pairs of mol-ecules ...
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In the title compound, C(9)H(7)N(3), the N-bound methyl group and vinyl H atom are syn. The 12 non-H atoms comprising the mol-ecule are essentially coplanar (r.m.s. deviation = 0.071 Å). Supra-molecular tapes feature in the crystal packing, orientated perpendicular to [10-1], and are formed by C-H⋯N inter-actions involving each cyano N atom. The tapes are connected into layers via π-π inter-act...
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ژورنال
عنوان ژورنال: Electrochemistry Communications
سال: 2010
ISSN: 1388-2481
DOI: 10.1016/j.elecom.2010.04.017